The suppliers website says this external gpu module is VR capable when connected through your TB3 port. So it should work with either a Rift S or Quest w/Link. Probably best to contact the supplier and ask for confirmation imho.
i9 13900K water cooled, RTX4090, Z790 MB w/wifi6e, 32Gb 6400 ram, 2x2TB SSD, 1000W PSU, Win 11, QPro, Q3, w/Link and Air Link, Vive Pro1 with 2x2.0 base stations, Etsy lens mod and Index Controllers